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Synthesis, Characterizations, and Quantum Chemical Investigations on Imidazo[1,2-<i>a</i>]pyrimidine-Schiff Base Derivative: (<i>E</i>)-2-Phenyl-<i>N</i>-(thiophen-2-ylmethylene)imidazo[1,2-<i>a</i>]pyrimidin-3-amine

Mohamed Azzouzi, Omar Azougagh, Abderrahim Ait Ouchaoui, Salah Eddine El Hadad, Stéphane Mazières, Soufian El Barkany, Mohamed Abboud, Adyl Oussaid

2023ACS Omega32 citationsDOIOpen Access PDF

Abstract

. Frontier molecular orbitals, molecular electrostatic potential, Mulliken atomic charge, electron localization function, localized orbital locator, natural bond orbital, nonlinear optical, Fukui functions, and quantum theory of atoms in molecules analyses are undertaken and meticulously interpreted, providing profound insights into the molecular nature and behaviors. In addition, ADMET and drug-likeness studies were carried out and investigated. Furthermore, molecular docking and molecular dynamics simulations have been studied, indicating that this is an ideal molecule to develop as a potential vascular endothelial growth factor receptor-2 inhibitor.

Topics & Concepts

ChemistryMolecular orbitalNatural bond orbitalComputational chemistrySchiff baseMoleculeDensity functional theoryMolecular geometryMulliken population analysisAtomic orbitalCarbon-13 NMRPyrimidineElectron localization functionMolecular dynamicsFragment molecular orbitalBasis setCrystallographyStereochemistryElectronPhysicsQuantum mechanicsOrganic chemistrySynthesis and biological activitySynthesis and Characterization of Heterocyclic CompoundsSynthesis of Tetrazole Derivatives
Synthesis, Characterizations, and Quantum Chemical Investigations on Imidazo[1,2-<i>a</i>]pyrimidine-Schiff Base Derivative: (<i>E</i>)-2-Phenyl-<i>N</i>-(thiophen-2-ylmethylene)imidazo[1,2-<i>a</i>]pyrimidin-3-amine | Litcius