Recent advances in the synthesis of nitrogen heterocycles <i>via</i> Rh(<scp>iii</scp>)-catalyzed chelation-assisted C–H activation/annulation with diazo compounds
Jidan Liu, Ruilian Liang, Yan Qu, Liyao Zheng, Zhao‐Qing Liu, Shouzhi Pu
Abstract
The advancements in the synthesis of nitrogen-containing heterocycles via Rh( iii )-catalyzed chelation-assisted tandem C–H activation/carbene insertion/annulation with diazo compounds as carbene precursors have been summarized.
Topics & Concepts
ChemistryDiazoAnnulationChelationCatalysisNitrogenMedicinal chemistryCombinatorial chemistryOrganic chemistryCatalytic C–H Functionalization MethodsCyclopropane Reaction Mechanisms