Substituted aromatic pentaphosphole ligands – a journey across the p-block
Christoph Riesinger, Gábor Balázs, Michael Seidl, Manfred Scheer
Abstract
R ligands in these compounds and multinuclear NMR spectroscopy confirms their integrity in solution. DFT calculations shed light on the bonding situation of these compounds and confirm the aromatic character of the pentaphosphole ligands on a journey across the p-block.
Topics & Concepts
ElectrophileSteric effectsChemistryCationic polymerizationReactivity (psychology)AromaticityStereochemistryNuclear magnetic resonance spectroscopyCrystallographyMedicinal chemistryMoleculeOrganic chemistryCatalysisPathologyMedicineAlternative medicineSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisFerrocene Chemistry and Applications