Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position
Y. Ávila, O. Pérez, L. C. Sánchez, M. C. Vázquez, R. Mojica, M. González, M. Ávila, J. Rodríguez‐Hernández, E. Reguera
Abstract
Thermally induced spin crossover in the Fe(3-hydroxypyridine) 2 [M(CN) 4 ] series with M = Ni, Pd, and Pt is reported. The role of the distortion of the iron atom coordination environment in the possibility of observing the spin crossover is explored.
Topics & Concepts
ChemistrySpin crossoverSubstituentCrossoverLigand (biochemistry)Coordination polymerAtom (system on chip)Spin (aerodynamics)CrystallographyDistortion (music)PolymerPosition (finance)StereochemistryCrystal structureOrganic chemistryThermodynamicsOptoelectronicsPhysicsReceptorFinanceAmplifierCMOSBiochemistryArtificial intelligenceComputer scienceEmbedded systemEconomicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies