Electrochemical Oxidative Phosphorylation of Aldehyde Hydrazones
Zhongnan Xu, Yueheng Li, Guangquan Mo, Yucheng Zheng, Shaogao Zeng, Pinghua Sun, Zhixiong Ruan
Abstract
The electrochemical phosphorylation of aldehyde hydrazones has been developed under exogenous oxidant-free conditions. The strategy provides expedient access to highly functionalized α-iminophosphine oxides with ample scope and broad functional group tolerance by means of mild, user-friendly electrolysis, in an undivided cell.
Topics & Concepts
ChemistryAldehydeOxidative phosphorylationElectrochemistryPhosphorylationElectrolysisScope (computer science)Combinatorial chemistryBulk electrolysisFunctional groupOrganic chemistryBiochemistryCatalysisComputer scienceCyclic voltammetryElectrodeElectrolytePhysical chemistryPolymerProgramming languageRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques