Impact of lanthanide ion complexation and temperature on the chemical reactivity of <i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-tetraoctyl diglycolamide (TODGA) with the dodecane radical cation
Gregory P. Horne, Cristian Celis‐Barros, Jacy K. Conrad, Travis S. Grimes, Jeffrey R. McLachlan, Brian M. Rotermund, Andrew R. Cook, Stephen P. Mezyk
Abstract
Ln( iii ) complexation by TODGA led to enhanced chemical reactivity with RH˙ + from electron pulse irradiation. Average local ionization energy calculations indicate that this enhancement is likely due to preferential reaction at nitrate counter ions.
Topics & Concepts
ChemistryLanthanideReactivity (psychology)Arrhenius equationLigand (biochemistry)RadiolysisPhysical chemistryInorganic chemistryIonActivation energyAqueous solutionOrganic chemistryReceptorBiochemistryAlternative medicinePathologyMedicineRadioactive element chemistry and processingLanthanide and Transition Metal ComplexesElectrochemical Analysis and Applications