Uncovering a CF<sub>3</sub> Effect on X‐ray Absorption Energies of [Cu(CF<sub>3</sub>)<sub>4</sub>]<sup>−</sup> and Related Copper Compounds by Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements**
Pinar Alayoglu, Tieyan Chang, Connly Yan, Yu‐Sheng Chen, Neal P. Mankad
Abstract
Abstract Understanding the electronic structures of high‐valent metal complexes aids the advancement of metal‐catalyzed cross coupling methodologies. A prototypical complex with formally high valency is [Cu(CF 3 ) 4 ] − ( 1 ), which has a formal Cu(III) oxidation state but whose physical analysis has led some to a Cu(I) assignment in an inverted ligand field model. Recent examinations of 1 by X‐ray spectroscopies have led previous authors to contradictory conclusions, motivating the re‐examination of its X‐ray absorption profile here by a complementary method, resonant diffraction anomalous fine structure (DAFS). From analysis of DAFS measurements for a series of seven mononuclear Cu complexes including 1 , here it is shown that there is a systematic trifluoromethyl effect on X‐ray absorption that blue shifts the resonant Cu K‐edge energy by 2–3 eV per CF 3 , completely accounting for observed changes in DAFS profiles between formally Cu(III) complexes like 1 and formally Cu(I) complexes like (Ph 3 P) 3 CuCF 3 ( 3 ). Thus, in agreement with the inverted ligand field model, the data presented herein imply that 1 is best described as containing a Cu(I) ion with d n count approaching 10.