Elemental sulfur as the “S” source: visible-light-mediated four-component reactions leading to thiocyanates
Zhiwei Wang, Ruisheng Liu, Chengming Qu, Xian‐En Zhao, Yufen Lv, Huilan Yue, Wei Wei
Abstract
An eco-friendly and photocatalyst-free visible-light-promoted four-component reaction of α-diazoesters, elemental sulfur, cyclic ethers and TMSCN leading to thiocyanates is described.
Topics & Concepts
ChemistrySulfurVisible spectrumComponent (thermodynamics)PhotocatalysisElemental analysisPhotochemistryOrganic chemistryCatalysisPhysicsThermodynamicsOptoelectronicsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsCyclopropane Reaction Mechanisms