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Progressive Increasing of Pt Nanoparticles with Multiple-Layered Manner inside Metal–Organic Frameworks for Enhanced Catalytic Activity

Yongxin Liu, Shan Wang, Bowen Yu, Yanshuang Zhang, Xiangyun Kong, Yaping Mi, Jiali Zhang, Zanru Guo, Wenyuan Xu, Xi Chen

2020Inorganic Chemistry12 citationsDOI

Abstract

Single-layered, double-layered, and triple-layered Pt nanoparticles with a well-defined arrangement were encapsulated inside metal-organic frameworks (MOFs) to investigate the catalytic performance influenced by the progressive increasing of Pt nanoparticles inside MOFs; the results show that the catalytic activity of the Pt-MOF hybrid catalysts increases progressively with the progressive increasing of the Pt nanoparticles inside MOFs. Progressive increasing of Pt nanoparticles with a multiple-layered manner inside MOFs provides a new route for designing well-organized hybrid catalysts of noble metal nanoparticles and MOFs with enhanced catalytic activity.

Topics & Concepts

ChemistryMetal-organic frameworkCatalysisNanoparticleNanotechnologyChemical engineeringOrganic chemistryAdsorptionMaterials scienceEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsNanomaterials for catalytic reactionsCatalytic Processes in Materials Science