Direct <i>N</i>-formylation of nitroarenes with CO<sub>2</sub>
Ni Shen, Shi‐Jing Zhai, Chi Wai Cheung, Jun‐An Ma
Abstract
to access N-aryl formamides exclusively in the presence of iron and hydrosilane as additives. This protocol showcases a good tolerance of a wide range of nitroarenes and nitroheteroarenes.
Topics & Concepts
FormylationChemistryOrganic chemistryCatalysisCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisMetal-Organic Frameworks: Synthesis and Applications