NIS-initiated photo-induced oxidative decarboxylative sulfoximidation of cinnamic acids
Nikita Chakraborty, Kamal Krishna Rajbongshi, Anjali Dahiya, Bubul Das, Akshar Vaishnani, Bhisma K. Patel
Abstract
-iodosulfoximine serves as the light-absorbing species in the absence of any external photosensitizer. The keto carbonyl and amidic carbonyl oxygen in the resulting product originate from dioxygen and water respectively.
Topics & Concepts
Cinnamic acidOxidative phosphorylationChemistryOxidative decarboxylationOxidative coupling of methaneDecarboxylationCinnamatesCombinatorial chemistryCatalysisOrganic chemistryPhotochemistryBiochemistrySynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsRadical Photochemical Reactions