Trifluoromethoxylation Reactions of (Hetero) arenes, Olefinic Systems and Aliphatic Saturated Substrates
Sebastián Barata‐Vallejo, Sergio M. Bonesi, Al Postigo
Abstract
Abstract Direct fluoroalkoxylation reactions of (hetero)arenes, carbon‐carbon multiple bonds, and substitution reactions at Csp 3 carbon centers by CF 3 O, CHF 2 O, and (CF 3 ) 2 CFO groups are discussed. Emphasis on thermal radical, electron transfer, photocatalytic, electrochemical and redox‐neutral radical methods are placed to accomplish fluoroalkoxylation reactions. All these methods employ either radical fluoroalkoxylating reagents or some nucleophilic trifluoromethoxylating sources of CF 3 O. A summary of all these methods is provided in Table 2.
Topics & Concepts
ChemistryReagentNucleophileRedoxElectron transferPhotochemistryElectrochemistryCarbon fibersNucleophilic substitutionSubstitution reactionRadicalPhotocatalysisPolymer chemistryOrganic chemistryCatalysisPhysical chemistryElectrodeMaterials scienceComposite materialComposite numberFluorine in Organic ChemistryInorganic Fluorides and Related CompoundsRadical Photochemical Reactions