Tunable Mechanical and Optoelectronic Properties of Organic Cocrystals by Unexpected Stacking Transformation from H- to J- and X-Aggregation
Wei Ji, Bin Xue, Santu Bera, Sarah Guerin, Yanqing Liu, Hui Yuan, Qi Li, Chengqian Yuan, Linda J. W. Shimon, Qing Ma, Evan Kiely, Syed A. M. Tofail, Mingsu Si, Xuehai Yan, Yi Cao, Wei Wang, Rusen Yang, Damien Thompson, Junbai Li, Ehud Gazit
Abstract
-acetyl-l-alanine (AcA), a nonaromatic amino acid derivative. This structural transformation into hybrid stacking mode improves physicochemical properties of the cocrystals, including a large red-shifted emission, enhanced supramolecular chirality, improved thermal stability, and higher mechanical properties. While a single crystal of 4,4'-Bpy shows good optical waveguiding and piezoelectric properties due to the uniform elongated needles and low symmetry of crystal packing, the significantly lower band gap and resistance of the cocrystal indicate improved conductivity. This study not only demonstrates cocrystallization-induced packing transformation between H-, J-, and X-aggregations in the solid state, leading to tunable mechanical and optoelectronic properties, but also will inspire future molecular design of organic functional materials by the coassembly strategy.