Synthesis, structure, and reactivity of uranium(<scp>vi</scp>) nitrides
Luciano Barluzzi, Fang‐Che Hsueh, Rosario Scopelliti, Benjamin E. Atkinson, Nikolas Kaltsoyannis, Marinella Mazzanti
Abstract
The first examples of molecular compounds containing the cyclic (U(<sc>vi</sc>)N)<sub>2</sub> and (U(<sc>v</sc>)U(<sc>vi</sc>)N)<sub>2</sub> cores were obtained by oxidation of the (U(<sc>v</sc>)U(<sc>v</sc>)N)<sub>2</sub> analogue. Different bonding within these complexes yields different stability and reactivity with CO and H<sub>2</sub>.
Topics & Concepts
HydrogenolysisReactivity (psychology)ChemistryNitrideUraniumYield (engineering)CatalysisMedicinal chemistryStereochemistryOrganic chemistryMaterials scienceMetallurgyLayer (electronics)Alternative medicinePathologyMedicineRadioactive element chemistry and processingCoordination Chemistry and OrganometallicsNuclear Materials and Properties