Modulating the frontier orbitals of L(X)Ga-substituted diphosphenes [L(X)GaP]<sub>2</sub>(X = Cl, Br) and their facile oxidation to radical cations
Mahendra K. Sharma, Sonia Chabbra, Christoph Wölper, Hanns M. Weinert, Edward J. Reijerse, Alexander Schnegg, Stephan Schulz
Abstract
(X = Cl 5a, Br 5b). Compounds 2-5 were fully characterized by NMR and IR spectroscopy as well as by single crystal X-ray diffraction (sc-XRD), and compounds 4a and 4b were further studied by EPR spectroscopy, while their bonding nature was investigated by DFT calculations.
Topics & Concepts
CarbeneChemistryReactivity (psychology)CrystallographyAtomic orbitalRedoxMolecular orbitalUnpaired electronMedicinal chemistryStereochemistryMoleculeInorganic chemistryElectronCatalysisOrganic chemistryMedicineQuantum mechanicsPathologyAlternative medicinePhysicsSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisOrganoboron and organosilicon chemistry