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14-electron reduced MoIV6-ε-Keggin polyoxometalates: highly stable and reversible electron/Li<sup>+</sup> sponge materials

Jie Zi, Meng Cao, Yu Fang, Cuiming Ren, Rui‐Li Sang, Li Xu

2023Inorganic Chemistry Frontiers12 citationsDOI

Abstract

14e-reduced hollow MoIV6-ε-Keggin POMs exhibit highly enhanced electrical conductivity and maintain their structural integrity during 24e-redox processes compared to fully oxidized POMs.

Topics & Concepts

RedoxElectronConductivityChemistryInorganic chemistryMaterials scienceElectrical resistivity and conductivityCrystallographyPhysical chemistryPhysicsQuantum mechanicsPolyoxometalates: Synthesis and ApplicationsSupercapacitor Materials and FabricationAdvanced battery technologies research
14-electron reduced MoIV6-ε-Keggin polyoxometalates: highly stable and reversible electron/Li<sup>+</sup> sponge materials | Litcius