Rigidified Derivative of the Non-macrocyclic Ligand H<sub>4</sub>OCTAPA for Stable Lanthanide(III) Complexation
Fátima Lucio‐Martínez, Zoltán Garda, Balázs Váradi, Ferenc K. Kálmán, David Esteban‐Gómez, Éva Tóth, Gyula Tircsó, Carlos Platas‐Iglesias
Abstract
complex. Complex dissociation occurs following proton- and metal-assisted pathways. The latter is relatively efficient at neutral pH, thanks to the formation of a heterodinuclear hydroxo complex.
Topics & Concepts
ChemistryLanthanideDissociation (chemistry)Density functional theoryLigand (biochemistry)MoleculeParamagnetismCoordination sphereMetalCrystallographyComputational chemistryIonPhysical chemistryOrganic chemistryBiochemistryQuantum mechanicsPhysicsReceptorLanthanide and Transition Metal ComplexesMagnetism in coordination complexesRadioactive element chemistry and processing