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Alkoxy-functionalized ionic liquid electrolytes: understanding ionic coordination of calcium ion speciation for the rational design of calcium electrolytes

Xinpei Gao, Xu Liu, Alessandro Mariani, Giuseppe Antonio Elia, Manuel Lechner, Carsten Streb, Stefano Passerini

2020Energy & Environmental Science72 citationsDOIOpen Access PDF

Abstract

The proof-of-concept demonstration of a rechargeable Ca/V<sub>2</sub>O<sub>5</sub> cell is given, taking advantage of an alkoxy-functionalized ionic liquid-based electrolyte enabling the displacement of the anions from the coordination of the Ca<sup>2+</sup> cations.

Topics & Concepts

Alkoxy groupElectrolyteIonic bondingIonic liquidInorganic chemistryChemistryCalciumIonCoordination numberRational designMaterials scienceOrganic chemistryPhysical chemistryNanotechnologyElectrodeAlkylCatalysisAdvanced Battery Materials and TechnologiesAdvanced battery technologies researchAdvancements in Battery Materials