Electrochemical energy storing performances of printed LaFeO3 coated with PEDOT: PSS for hybrid supercapacitors
Reshma Nair, Kiranmai Uppuluri, Febin Paul, Keith Sirengo, D. Szwagierczak, Suresh C. Pillai, Libu Manjakkal
Abstract
• Preparation of new perovskite materials for electrochemical energy storage. • Screen-printed LaFeO 3 perovskite for the next generation of supercapacitors. • Enhancement of energy storing by surface coating of LaFeO 3 with PEDOT:PSS. • Influence of sintering temperature of LaFeO 3 on enhanced energy storage device. • LaFeO 3 modified with PEDOT: PSS exhibited a specific capacitance of 12.01 mF∙cm −2 . Developing advanced smart energy storage devices demanded new functional materials to store energy effectively and deliver power quickly. In this work, we studied the energy-storing performance of perovskite material, lanthanum ferrite (LaFeO 3 ), prepared by the solid-state reaction method. The screen-printed LaFeO 3 and graphite electrodes are used to develop hybrid supercapacitors (HSCs) with KOH electrolyte. Varying the sintering temperature of the LaFeO 3 perovskite electrode (800 °C, 900 °C, and 1000 °C) leads to changes in the surface and crystalline properties, which impact the electrochemical properties and overall energy-storing performance of the HSC. The surface of the LaFeO 3 electrode is modified with organic conducting polymer poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS), which enhances the energy storage of the HSC. The developed HSC based on LaFeO 3 , sintered at 1000 °C and surface modified with PEDOT: PSS, exhibited a specific capacitance of 12.007 mF∙cm −2 at a current density of 0.075 mA∙cm −2 . This value is two times higher than (5.874 mF∙cm −2 ) without the surface modification of LaFeO 3 at 1000 °C. This study provides valuable insights into the electrochemical performances of the ABO 3 perovskite (LaFeO 3 ) electrodes for the next generation of portable energy storage devices.