Implanting <scp>MoS<sub>2</sub></scp> quantum dots on <scp>MgB<sub>2</sub></scp> nanosheets for lithium–sulfur batteries
Xiaodong Zhu, Caidi Han, Jinhao Zhang, Wanliang Mi, Yingtai Qin, Jian Gao, Jinting Wu, Ji‐Jun Zou, Xiaoxuan Yang, Yongchao Zhang, Gang Wu
Abstract
Abstract As a new generation of high‐efficiency energy storage devices, lithium–sulfur (Li–S) battery attract increasing attention. However, slow conversion kinetics of lithium polysulfides (LiPSs) and severe shuttle effect are bottlenecks. Developing efficient sulfur host materials to suppress the shuttling of LiPSs and accelerate their conversion kinetics is a general strategy to enhance the performance of Li–S batteries. Herein, MoS 2 quantum dots (QDs)@MgB 2 nanosheet was synthesized using a simple liquid‐phase mixing method. The MoS 2 QDs not only inhibit the stacking of MgB 2 nanosheets but also expose more unsaturated metal active sites, which can effectively improve the adsorption of LiPSs, accelerate its catalytic conversion and suppress its shuttle effect. Moreover, MgB 2 nanosheets can be used as polypropylene (PP) separator modifier. The battery using MoS 2 QDs@MgB 2 as the sulfur host material and MgB 2 @PP as the separator has high rate capability and excellent stability. In addition, the discharge‐specific capacity shows a good application prospect. image