Binders from gypsum-containing waste and products based on them
Nataliya Alfimova, Севда Пириева, M.Yu. Elistratkin, I. S. Nikulin, A A Titenko
Abstract
Abstract Gypsum binders are among the most environmentally friendly from the point of view of their production. The raw material base for their production is represented not only by natural raw materials, but also by a wide variety of technogenic materials, phosphogypsum is the most multi-ton and studied of them. At the same time, citrogypsum is also a promising raw material for the production of gypsum binders and, in comparison with phosphogypsum, does not contain toxic impurities that require the development of additional measures for their removal. Synthesis of the binder from gypsum-containing waste is possible with the use of various technologies using autoclaves, chemical reagents and at elevated temperature and atmospheric pressure. Each method has its own advantages and disadvantages. The most acceptable from the point of view of industrial production is the method of calcination at atmospheric pressure, but it does not allow producing high-strength binders and products based on them. It is possible to increase the efficiency of using such binders for the production of small-piece products by applying special molding modes with increased pressing pressure. The possibility of obtaining a binder from the waste of citric acid – citrogypsum production by calcination in a semi-industrial plant is shown. Using standard methods, a complete analysis of the resulting binder was performed: granulometry, grain shape and morphology, normal density and setting time. A comparison was made with construction gypsum (G5) and high-strength gypsum (G16). The possibility of obtaining small – piece products from a synthesized binder with a dry compressive strength of 20 MPa is shown by using the semi-dry pressing method at high pressures.