Unimolecular cooperative metallaphotocatalysis with conjugately bridged Ir–Ni complexes and its applications in organic coupling reactions
Mahesh Bhagwan Thoke, Gui‐Jun Sun, Rahul Anil Borse, Ping Lin, Shao-Xia Lin
Abstract
The novel unimolecular Ir-Ni bimetallic system with the conjugated bridging ligand has been developed. Photoinduced cross-coupling reactions (C–O, C–S, C–N) demonstrated the enormous potential of a conjugately bridged Ir–Ni catalytic system.
Topics & Concepts
Bimetallic stripChemistryConjugated systemCoupling reactionBridging ligandCatalysisBridging (networking)Ligand (biochemistry)PhotochemistryCoupling (piping)Polymer chemistryCombinatorial chemistryCrystallographyOrganic chemistryCrystal structurePolymerComputer networkMechanical engineeringReceptorEngineeringComputer scienceBiochemistryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions