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New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution

Guanglian Sun, Xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

2024Inorganic Chemistry Frontiers13 citationsDOIOpen Access PDF

Abstract

In the three structures, the substitution of large-size cations results in the rearrangement of the anionic group, and their birefringence exhibits a progressive doubling increase, transitioning from 0.017, 0.033 to 0.070 at 532 nm.

Topics & Concepts

Substitution (logic)BirefringenceBoronRare earthUltravioletMaterials scienceSubstitution effectCrystallographyChemistryPhotochemistryInorganic chemistryOpticsOptoelectronicsOrganic chemistryMetallurgyPhysicsComputer scienceNeoclassical economicsProgramming languageEconomicsCrystal Structures and PropertiesLuminescence Properties of Advanced MaterialsInorganic Fluorides and Related Compounds