Litcius/Paper detail

Polypyrrole decorated metal–organic frameworks for supercapacitor devices

Nigel Patterson, Bo Xiao, Anna Ignaszak

2020RSC Advances61 citationsDOIOpen Access PDF

Abstract

). The maximum operating potential for these electrodes is 0.5 V, which is restricted by the contact of MOF with aqueous electrolyte and with extremely low PPy content. As a solution, higher PPy loading and rational adjustment of particle size and porosity of both MOF and PPy are recommended so that the MOF/electrolyte interface is limited, leading to more robust electrode. The work completed here describes a highly promising approach to tackling the electrically insulating nature of MOFs, paving the way for their use in electrochemical energy storage devices.

Topics & Concepts

PolypyrroleSupercapacitorMetal-organic frameworkMaterials scienceGravimetric analysisElectrolyteChemical engineeringCapacitancePorosityConductive polymerConductivityElectrodeSpecific surface areaPolymerChemistryComposite materialCatalysisAdsorptionOrganic chemistryPolymerizationPhysical chemistryEngineeringSupercapacitor Materials and FabricationMetal-Organic Frameworks: Synthesis and ApplicationsConducting polymers and applications