Bis(NHC)-Pd-catalyzed one-pot competitive C–CC–C, C–CC–O, C–CC–N, and C–OC–N cross-coupling reactions on an aryl di-halide catalyzed by a homogenous basic ionic liquid (TAIm[OH]) under base-free, ligand-free, and solvent-free conditions

Yanfang Zhu, Guiyang Xu, Milad Kazemnejadi

2021New Journal of Chemistry25 citationsDOI

Abstract

A new ionic liquid with intrinsic basic, ligand, and solvent properties is developed for efficient and selective Pd-catalyzed asymmetric C–C, C–O, and C–N cross-coupling reactions under mild conditions.

Topics & Concepts

ChemistryCatalysisHalideArylLigand (biochemistry)Medicinal chemistryCoupling reactionSolventCoupling (piping)StereochemistryOrganic chemistryAlkylReceptorMechanical engineeringEngineeringBiochemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis

Bis(NHC)-Pd-catalyzed one-pot competitive C–C*C–C, C–C*C–O, C–C*C–N, and C–O*C–N cross-coupling reactions on an aryl di-halide catalyzed by a homogenous basic ionic liquid (TAIm[OH]) under base-free, ligand-free, and solvent-free conditions

Abstract

Topics & Concepts

Bis(NHC)-Pd-catalyzed one-pot competitive C–CC–C, C–CC–O, C–CC–N, and C–OC–N cross-coupling reactions on an aryl di-halide catalyzed by a homogenous basic ionic liquid (TAIm[OH]) under base-free, ligand-free, and solvent-free conditions