Structure, assembly mechanism and magnetic properties of heterometallic dodecanuclear nanoclusters DyIII4MII8 (M = Ni, Co)
Shui Yu, Qinhua Zhang, Zilu Chen, Hua‐Hong Zou, Huancheng Hu, Dongcheng Liu, Fu‐Pei Liang
Abstract
Two isostructural heterometallic dodecanuclear nanoclusters [Dy 4 Co 8 (μ 3 -OH) 8 (L) 8 (OAc) 4 (H 2 O) 4 ]·3EtOH·3CH 3 CN·H 2 O (1) and [Dy 4 Ni 8 (μ 3 -OH) 8 (L) 8 (OAc) 4 (H 2 O) 4 ]·3.5EtOH·0.5CH 3 CN·5H 2 O (2) with different assembly mechanisms are presented here.
Topics & Concepts
IsostructuralNanoclustersCrystallographyChemistryMaterials scienceCrystal structureNanotechnologyMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms