Metal-coordinated distibene and dibismuthene dications – isoelectronic analogues of butadiene dications
Hanns M. Weinert, Yannick Schulte, Alexander Gehlhaar, Christoph Wölper, Gebhard Haberhauer, Stephan Schulz
Abstract
Salt metathesis of L(TfO)Ga-substituted dipnictenes allowed for the synthesis of heavy dipnictene dications, which can be considered as isoelectronic analogues of the butadiene dication.
Topics & Concepts
ChemistryMetal1,3-ButadieneComputational chemistryOrganic chemistryCatalysisSynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisCoordination Chemistry and Organometallics