Donor–acceptor covalent organic framework promotes visible light-induced oxidative coupling of amines to imines in air
Jingwen Feng, Jie Cheng, Jun Pang, Mingqiang Tang, Zewei Liu, Chunying Rong, Rong Tan
Abstract
The donor–acceptor COF greatly improved light harvesting and charge separation through a push–pull electron effect, realizing the efficient oxidative coupling of amines to imines with air under visible light irradiation.
Topics & Concepts
Oxidative coupling of methanePhotochemistryCovalent bondAcceptorCovalent organic frameworkElectron acceptorCoupling (piping)ChemistryVisible spectrumOxidative phosphorylationCatalysisCharge (physics)IrradiationElectron donorMaterials scienceOptoelectronicsOrganic chemistryQuantum mechanicsNuclear physicsBiochemistryMetallurgyCondensed matter physicsPhysicsCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications