Fine-tuning the pore structure of metal–organic frameworks by linker substitution for enhanced hydrogen storage and gas separation
Xiwei Han, Xiaoxian Yang, Chuan Yu, Shuyan Lu, Ehsan Sadeghi Pouya, Peng Bai, Jiafei Lyu, Xianghai Guo
Abstract
The functionalized Zr-MOFs with narrowed cavities and exposed sites exhibit improved H<sub>2</sub> storage and adsorption selectivity towards binary mixtures.
Topics & Concepts
Hydrogen storageLinkerSubstitution (logic)Metal-organic frameworkMaterials scienceHydrogenGas separationMetalChemical engineeringChemistryOrganic chemistryMetallurgyComputer scienceAdsorptionOperating systemBiochemistryEngineeringMembraneProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMembrane Separation and Gas Transport