β-Bis-CF<sub>3</sub>-substituted phosphorus corroles, theory and experiments
Xuan Zhan, Zakir Ullah, Donghyeon Kim, Bilal Mustafa, Hyung Wook Kwon, David G. Churchill, Zeev Gross
Abstract
All constitutional isomers of beta bis-CF 3 substituted (tpfc)PF2 were geometrically optimized and studied electronically. The six synthetically accessed compounds were characterized (of the 18 possible) by NMR spectroscopy and other techniques.
Topics & Concepts
PhosphorusChemistrySpectroscopyNuclear magnetic resonance spectroscopyComputational chemistryCombinatorial chemistryStereochemistryOrganic chemistryPhysicsQuantum mechanicsPorphyrin and Phthalocyanine ChemistryFluorine in Organic ChemistryInorganic Fluorides and Related Compounds