Effect of Position of Donor Units and Alkyl Groups on Dye-Sensitized Solar Cell Device Performance: Indoline–Aniline Donor-Based Visible Light Active Unsymmetrical Squaraine Dyes
Amrita Singh, Ambarish Kumar Singh, Ruchi Dixit, Kumar Vanka, Kothandam Krishnamoorthy, Jayaraj Nithyanandhan
Abstract
High Resolution Image Download MS PowerPoint Slide Indoline (In) and aniline (An) donor-based visible light active unsymmetrical squaraine (SQ) dyes were synthesized for dye-sensitized solar cells (DSSCs), where the position of An and In units was changed with respect to the anchoring group (carboxylic acid) to have In-SQ-An-CO 2 H and An-SQ-In-CO 2 H sensitizers, AS1–AS5 . Linear or branched alkyl groups were functionalized with the N atom of either In or An units to control the aggregation of the dyes on TiO 2 . AS1–AS5 exhibit an isomeric π-framework where the squaric acid unit is placed in the middle, where AS2 and AS5 dyes possess the anchoring group connected with the An donor, and AS1, AS3, and AS4 dyes having the anchoring group connected with the In donor. Hence, the conjugation between the middle squaric acid acceptor unit and the anchoring −CO 2 H group is short for AS2, AS5, and AK2 and longer for AS1, AS3, and AS4 dyes. AS dyes showed absorption between 501 and 535 nm with extinction coefficients of 1.46–1.61 × 10 5 M –1 cm –1 . Further, the isomeric π-framework of An-SQ-In-CO 2 H and In-SQ-An-CO 2 H exhibited by means of changing the position of In and An units a bathochromic shift in the absorption properties of AS2 and AS5 compared to the AS1, AS3, and AS4 dyes. The DSSC device fabricated with the dyes contains short acceptor-anchoring group distance ( AS2 and AS5 ) showed high photovoltaic performances compared to the dyes having longer distance ( AS1, AS3, and AS4 ) with the iodolyte (I – /I 3 – ) electrolyte. DSSC device efficiencies of 5.49, 6.34, 6.16, and 5.57% have been achieved for AS1, AS2, AS3, and AS4 dyes, respectively; without chenodeoxycholic acid (CDCA), small changes have been observed in the device performance of the AS dyes with CDCA. Significant changes have been noted in the DSSC parameters (open-circuit voltage V OC, short-circuit current J SC, fill factor ff, and efficiency η) for the AS5 dye while sensitized with CDCA and showed highest DSSC efficiency of 8.01% in the AS dye series. This study revealed the potential of shorter SQ acceptor-anchoring group distance over the longer one and the importance of alkyl groups on the overall DSSC device performance for the unsymmetrical squaraine dyes.