Modulator-free approach towards missing-cluster defect formation in Zr-based UiO-66
Patchanee Chammingkwan, Goji Yildun Shangkum, Le Thi Tuyet Mai, Priyank Mohan, Ashutosh Thakur, Toru Wada, Toshiaki Taniike
Abstract
By rigorous control of water, missing-cluster defects in Zr-based UiO-66 were generated to a remarkable extent without the need of acidic modulators. The presence of missing-cluster defects created hierarchical pore structures, which had a profound effect on the catalytic performance.
Topics & Concepts
Cluster (spacecraft)ChemistryMaterials scienceComputer scienceComputer networkMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceX-ray Diffraction in Crystallography