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Electroactive Covalent Organic Frameworks: Design, Synthesis, and Applications

Yusran Yusran, Qianrong Fang, Valentin Valtchev

2020Advanced Materials211 citationsDOIOpen Access PDF

Abstract

Covalent organic frameworks (COFs) are an emerging class of crystalline porous polymers with tailorable compositions, porosities, functionalities, and intrinsic chemical stability. The incorporation of electroactive moieties in the structure transforms COFs into electroactive materials with great potential for energy-related applications. Herein, the recent advances in the design and use of electroactive COFs as capacitors, batteries, conductors, fuel cells, water-splitting, and electrocatalysis are addressed. Their remarkable performance is discussed and compared with other porous materials; hence, perspectives in the development of electroactive COFs are presented.

Topics & Concepts

Materials scienceCovalent bondNanotechnologyElectrocatalystElectroactive polymersPolymerPorosityCapacitorConductive polymerElectrochemistryElectrodeOrganic chemistryVoltageChemistryComposite materialElectrical engineeringEngineeringPhysical chemistryCovalent Organic Framework ApplicationsAdvanced battery technologies researchConducting polymers and applications