Synthesis, X-ray characterization and regium bonding interactions of a trichlorido(1-hexylcytosine)gold(<scp>iii</scp>) complex
Ángel Terrón, Jordi Buils, Tiddo J. Mooibroek, Miquel Barceló‐Oliver, A. García‐Raso, J.J. Fiol, Antonio Frontera
Abstract
N complexes stack on top of each other by reciprocal [AuCl] regium bonding interactions. After the first example 35 years ago, this is the second available structure of a cytosine nucleobase model complexed to gold(iii).
Topics & Concepts
Characterization (materials science)CrystallographyNucleobaseChemistryStereochemistryGold CompoundsNanotechnologyCombinatorial chemistryDNAMaterials scienceBiochemistryMetal complexes synthesis and propertiesOrganometallic Complex Synthesis and CatalysisNanocluster Synthesis and Applications