The impact of alicyclic substituents on the extraction ability of new family of 1,10-phenanthroline-2,9-diamides
Pavel S. Lemport, Petr I. Matveev, A. V. Yatsenko, Mariia V. Evsiunina, V. S. Petrov, Борис Н. Тарасевич, Vitaly A. Roznyatovsky, Павел В. Дороватовский, Victor N. Khrustalev, Sergey S Zhokhov, Vitaly P. Solov’ev, L. A. Aslanov, Vladimir G. Petrov, Stepan N. Kalmykov, Valentine G. Nenajdenko, Yuri A. Ustyniuk
Abstract
'-tetraalkyl analogues. The structures of synthesized compounds were studied in details by IR, NMR spectroscopy, and single crystal X-ray diffraction. According to spectroscopy data, incorporation of aromatic rings to the amide fragment of ligand leads to complex dynamic behavior in solutions what is believed to strongly affect the extraction ability of synthesized ligands.
Topics & Concepts
ChemistryAmericiumLanthanideSelectivityPhenanthrolineAmideExtraction (chemistry)ActinideCuriumMicroporous materialLigand (biochemistry)SpectroscopyInorganic chemistryOrganic chemistryIonCatalysisQuantum mechanicsReceptorBiochemistryPhysicsRadioactive element chemistry and processingChemical Synthesis and CharacterizationNuclear materials and radiation effects