Deaggregation properties and transmetalation studies of a zinc(<scp>ii</scp>) salen-type Schiff-base complex
Ivan Pietro Oliveri, Giuseppe Consiglio, Gabriella Munzi, Salvatore Failla, Santo Di Bella
Abstract
), indicating the role of the chloride in stabilizing the transition state of the transmetalation. On the other hand, DMF solutions of the complex are less prone to transmetalation, according with the greater basicity of the solvent and, hence, the greater stability of the related adducts with the complex. Therefore, the nature of the solvent and the counteranion allow controlling the transmetalation process of this Zn(II) Schiff-base complex.
Topics & Concepts
TransmetalationChemistrySchiff baseAdductPolymer chemistryInorganic chemistryLewis acids and basesMetalationSolventPerchlorateMedicinal chemistryOrganic chemistryCatalysisIonCrystal structures of chemical compoundsMetal complexes synthesis and propertiesSupramolecular Chemistry and Complexes