Defect Engineering in a Eu<sup>2+</sup>-Doped β-Al<sub>2</sub>O<sub>3</sub> Structure Blue Phosphor and Its Controllable Zero-Thermal Quenching Luminescence
Siqi Piao, Yichao Wang, Xufeng Zhou, Wanying Geng, Jinsu Zhang, Xizhen Zhang, Danyang Wu, Yongze Cao, Xiangping Li, Baojiu Chen
Abstract
A series of K1–2x–2yBayAl11O17(KBAO):xEu2+ phosphors are designed to develop a blue phosphor with excellent thermal properties. All of the samples present similar β-Al2O3 structures with P63/mmc space group; the K+ vacancy can exist stably until the Ba2+ concentration exceeds around y = 0.3. KBAO:Eu2+ exhibits strong absorption for near-ultraviolet light and relatively standard blue emission. The mechanisms for excitation and emission spectrum variations have also been studied in detail. Based on the adjustment of K+ vacancy numbers in the defect structure, K0.6Ba0.1Eu0.1Al11O17 exhibits a remarkable quantum yield of around 91.2% and a terrific high-temperature characteristic. The zero-thermal quenching performance mainly results from stabilization of the flowing electron number between Eu2+ 5d levels and K+ defect ε(0/–1) and ε(+1/0) levels in the processes of thermal ionization and recombination. A bright fabricated white-light-emitting diode (WLED) gives a color rendering index (CRI) of Ra = 87 and a correlated color temperature (CCT) of 4510 K, demonstrating that KBAO:Eu2+ has application potential to provide a blue light component in WLED. In addition, our research is a significant attempt to achieving stable zero-thermal quenching by subjective structure design, which provides a reference value for investigating the excellent new phosphors.