The principle of detailed balancing, the iron-catalyzed disproportionation of hydrogen peroxide, and the Fenton reaction
David M. Stanbury
Abstract
Over 200 publications report mechanisms that violate the principle of detailed balancing; a 10-step core mechanism is proposed that avoids these problems.
Topics & Concepts
DisproportionationCatalysisChemistryHydrogen peroxideReaction rate constantDecompositionReaction rateComputational chemistryCombinatorial chemistryPhotochemistryKineticsOrganic chemistryPhysicsQuantum mechanicsAdvanced oxidation water treatmentElectrochemical Analysis and ApplicationsElectrocatalysts for Energy Conversion