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Carbon monoxide and hydrogen (syngas) as a C1-building block for selective catalytic methylation

Akash Kaithal, Markus Hölscher, Walter Leitner

2020Chemical Science35 citationsDOIOpen Access PDF

Abstract

A broadly applicable catalytic process for the selective β-methylation of alcohols is presented using syngas (CO/H 2 ) directly as a C1 building block and the shown manganese complex in the presence of a base as the catalytic system.

Topics & Concepts

SyngasCarbon monoxideCatalysisHydrogenChemistrySyngas to gasoline plusBlock (permutation group theory)MethylationHydrogen productionOrganic chemistrySteam reformingBiochemistryMathematicsGeometryGeneCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisCatalysts for Methane Reforming
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