Pushing the Limits: Down‐Converting Er<sup>3+</sup>‐Doped BaF<sub>2</sub> Single Crystals with Photoluminescence Quantum Yield Surpassing 100%
Eduard Madirov, С. В. Кузнецов, Vasilii A. Konyushkin, Dmitry Busko, Bryce S. Richards, Andrey Turshatov
Abstract
Abstract Down‐conversion (DC) is a phenomenon that can enable the observation of photoluminescent quantum yield (PLQY) values exceeding 100%. A comprehensive study of the DC properties of BaF 2 –based single crystals with different Er 3+ doping levels (1–25 mol.%) is presented. The samples exhibit a PLQY of 110% in the 1550–1650 nm under 405 nm excitation. This remarkable PLQY is attributed to a cross‐relaxation process within the energy levels of Er 3+ . Furthermore, when considering all emitted photons in the 1000–1650 nm range, the PLQY reaches 153% for a sample doped with 5 mol.% of Er 3+ . By integrating the emission of this single crystal with a Ge diode, serving as an example of a photovoltaic device sensitive to short‐wave infrared light, a significant enhancement in short‐circuit current is demonstrated. In a broader context, the presented material holds promise for improving the spectral response of low‐bandgap photovoltaic devices.