Zero-field slow magnetic relaxation behavior of Zn<sub>2</sub>Dy in a family of trinuclear near-linear Zn<sub>2</sub>Ln complexes: synthesis, experimental and theoretical investigations
Naushad Ahmed, Kamal Uddin Ansari
Abstract
In the series of Schiff base supported Zn 2 Ln complexes 1-La–6-Dy, the SIM behavior observed only for 6-Dy ( U eff = 43.7 K). The ab initio theoretical calculations rationalized the experimentally observed magnetic behaviors for all.
Topics & Concepts
MagnetizationRelaxation (psychology)IonExcited stateChemistryAb initioCrystallographyGround stateAb initio quantum chemistry methodsLanthanideField (mathematics)Condensed matter physicsMaterials scienceMagnetic fieldAtomic physicsMoleculePhysicsOrganic chemistryMathematicsSocial psychologyPure mathematicsPsychologyQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies