Photochemical transformation of anthracene (ANT) in surface soil: Chlorination and hydroxylation
Zhengnan Tu, Yumeng Qi, Xiaosheng Tang, Zunyao Wang, Ruijuan Qu
Abstract
To reveal the fate of anthracene (ANT) in soil, the photodegradation behavior of ANT was systematically studied using SiO 2 to simulate a soil environment. Under xenon lamp irradiation, more than 90% of ANT loaded on SiO 2 could be removed after 240 min. Moreover, the effects of water content, chloride ions (Cl - ) and humic acid (HA) were examined. It was found that the presence of water and HA can significantly inhibit the photolysis of ANT on SiO 2 , while the addition of chloride alone has no obvious effect. However, when water is present, the inhibition effect of chloride became more obvious. According to radical quenching experiments and electron paramagnetic resonance (EPR) spectra, hydroxyl radicals (•OH) and chlorine radicals (Cl•) were formed in the system. Possible reaction pathways were speculated based on products identified by mass spectrometry . ANT was attacked by •OH to form hydroxylated products, which can be further hydroxylated and oxidized with the final formation of ring-opening products. ANT directly excited by light may also react with Cl• to produce chlorinated polycyclic aromatic hydrocarbons (Cl-PAHs). Finally, the experimental results were verified on real soil. This study provides important information for understanding the photochemical transformation mechanism of ANT at the soil/air interface.