1D van der Waals Nb<sub>2</sub>Pd<sub>3</sub>Se<sub>8</sub>‐Based n‐Type Field‐Effect Transistors Prepared by Liquid Phase Exfoliation
Kyung Hwan Choi, Jiho Jeon, Byung Joo Jeong, Sudong Chae, Seungbae Oh, Chaeheon Woo, Tae Yeong Kim, Jungyoon Ahn, Jae‐Hyun Lee, Hak Ki Yu, Jae‐Young Choi
Abstract
Abstract Recently, the 1D ternary transition metal chalcogenide Nb 2 Pd 3 Se 8 has been reported as a promising channel material for the field‐effect transistors (FETs) with high performance transport behavior. Its structural characteristic of weak van der Waals (vdW) forces between unit ribbons allows for the isolation of high quality Nb 2 Pd 3 Se 8 nanowires from the bulk crystal that are similar to typical layered 2D materials. This study reports on the liquid phase exfoliation (LPE) of 1D vdW Nb 2 Pd 3 Se 8 to predict the optimal solvent in terms of the total surface tension and polar/dispersive component ratio. Among the various test solvents, N ‐methyl‐2‐pyrrolidone and dimethylformamide are found to be the best solvents for the exfoliation and stabilization of the Nb 2 Pd 3 Se 8 nanowires due to their well‐matched total surface tensions and polar/dispersive component ratios. Additionally, FETs are fabricated on the LPE‐processed Nb 2 Pd 3 Se 8 nanowires, and the charge transport behavior is characterized at room temperature. The FETs exhibit n‐type characteristics with an I on / I off ratio and field‐effect mobility up to ≈10 3 and 15 cm 2 V −1 s −1 . This study on the LPE of novel Nb 2 Pd 3 Se 8 nanowires is an important step toward various practical applications in nanoelectronics.