A highly robust cluster-based indium(<scp>iii</scp>)–organic framework with efficient catalytic activity in cycloaddition of CO<sub>2</sub> and Knoevenagel condensation
Hongxiao Lv, Liming Fan, Tuoping Hu, Chenxu Jiao, Xiutang Zhang
Abstract
The exquisite combination of [In 4 (μ 3 -OH) 2 (COO) 10 (DMF)(H 2 O) 2 ] clusters and H 5 CPDD generated a highly robust nanoporous MOF with high catalytic performance in the cycloaddition reaction of epoxides with CO 2 and Knoevenagel condensation.
Topics & Concepts
Knoevenagel condensationCatalysisChemistryCycloadditionLewis acids and basesMoleculeStackingMetal-organic frameworkBifunctionalCombinatorial chemistryAdsorptionPhysical chemistryOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications