Unveiling the fundamental understanding of two dimensional π-conjugated FeN<sub>4+4</sub> sites for boosting peroxymonosulfate activation
Sijia Jin, Wenxian Tan, Xiaofeng Tang, Xia Yao, Yingjian Bao, Haiyan Zhang, Shuang Song, Tao Zeng
Abstract
The precisely defined FeN 4+4 active sites in fully π-conjugated polyphthalocyanine frameworks establish a dual-pump-driven electron fast shuttle path—electron-rich Fe centers and electron-poor C atoms—ensuring continuous production of 1 O 2 .
Topics & Concepts
Conjugated systemBoosting (machine learning)ChemistryComputer scienceArtificial intelligenceOrganic chemistryPolymerAdvanced Nanomaterials in CatalysisWater Quality Monitoring and Analysis