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Recent Advances and Outlook for the Isosteric Replacement of Anilines

Taylor Sodano, Logan A. Combee, Corey R. J. Stephenson

2020ACS Medicinal Chemistry Letters70 citationsDOIOpen Access PDF

Abstract

Many promising drug candidates and pharmaceutical compounds fail due to idiosyncratic adverse drug reactions (IADRs), often arising from the formation of reactive metabolites. Among the "structural alerts" responsible, anilines are well-known to undergo deleterious metabolic processing, yet isosteric replacement strategies remain limited. Herein we discuss current art and potential new avenues of saturated isosteres to mitigate aniline-related toxicities.

Topics & Concepts

Computer scienceData scienceChemical Synthesis and ReactionsChemical Synthesis and AnalysisAsymmetric Hydrogenation and Catalysis
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