Sub parts-per-billion detection of ethane in a 30-meters long mid-IR Antiresonant Hollow-Core Fiber
Piotr Jaworski, Karol Krzempek, Paweł Kozioł, Dakun Wu, Fei Yu, Piotr Bojęś, Grzegorz Dudzik, Meisong Liao, J. C. Knight, Krzysztof M. Abramski
Abstract
In this work, we present the first demonstration of a gas sensor utilizing the Wavelength Modulation Spectroscopy technique and a mid-IR guiding Antiresonant Hollow-Core Fiber with a record length of 30 m. The self-fabricated ARHCF was used as an air-tight, low-volume absorption cell delivering an extended laser-gas molecules interaction path within the sensor’s setup, which enabled it to efficiently detect ethane at 2996.88 cm−1. Benefiting from the unique guidance properties of the ARHCF, the sensor reached a minimum detection limit of 670 parts-per-trillion by volume for 14 s integration time, which is at a level comparable to the bulk optics-based systems utilizing more complex detection techniques or multipass cells with tens of meters long optical path lengths. The obtained results confirm that ARHCF-based gas sensors can successfully compete with or even outperform bulk optics-based mid-IR gas sensor configurations. The obtained results show the potential for the development of novel, low-volume, compact, and reliable types of gas detectors allowing precise analysis of various gaseous substances at their trace concentration level.