Topology- and wavelength-governed CO<sub>2</sub> reduction photocatalysis in molecular catalyst-metal–organic framework assemblies
Philip M. Stanley, Karina Hemmer, Markus Hegelmann, Annika Schulz, Mihyun Park, Martin Elsner, Mirza Cokoja, Julien Warnan
Abstract
reduction product selectivity is governed by selective activation of two independent, circumscribed or delocalised, energy/electron transfer channels from the porphyrin excited state to either formate-producing MOF nodes or the CO-producing molecular catalysts.
Topics & Concepts
PhotocatalysisCatalysisTopology (electrical circuits)Reduction (mathematics)MetalMaterials scienceMetal-organic frameworkWavelengthChemical engineeringNanotechnologyChemistryOrganic chemistryOptoelectronicsEngineeringMathematicsElectrical engineeringMetallurgyAdsorptionGeometryMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsAdvanced Photocatalysis Techniques