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Biomass-Derived Activated Carbon as a Catalyst for the Effective Degradation of Rhodamine B dye

Shamim Ahmed Hira, Mohammad Yusuf, Dicky Annas, Hu Hui, Kang Hyun Park

2020Processes27 citationsDOIOpen Access PDF

Abstract

Activated carbon (AC) was fabricated from carrot waste using ZnCl2 as the activating agent and calcined at 700 °C for 2 h in a tube furnace. The as-synthesized AC was characterized using Fourier-transform infrared spectroscopy, X-ray diffraction analysis, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller analysis; the results revealed that it exhibited a high specific surface area and high porosity. Moreover, this material displayed superior catalytic activity for the degradation of toxic Rhodamine B (RhB) dye. Rate constant for the degradation of RhB was ascertained at different experimental conditions. Lastly, we used the Arrhenius equation and determined that the activation energy for the decomposition of RhB using AC was approximately 35.9 kJ mol−1, which was very low. Hopefully it will create a great platform for the degradation of other toxic dye in near future.

Topics & Concepts

Rhodamine BFourier transform infrared spectroscopyX-ray photoelectron spectroscopyCalcinationDegradation (telecommunications)Activated carbonCatalysisScanning electron microscopeMaterials scienceArrhenius equationDecompositionTransmission electron microscopyChemical engineeringNuclear chemistryAnalytical Chemistry (journal)ChemistryActivation energyNanotechnologyAdsorptionPhotocatalysisComposite materialOrganic chemistryEngineeringComputer scienceTelecommunicationsAdsorption and biosorption for pollutant removalNanomaterials for catalytic reactionsCarbon and Quantum Dots Applications
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