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Tandem sequential catalytic enantioselective synthesis of highly-functionalised tetrahydroindolizine derivatives

Shuyue Zhang, Mark D. Greenhalgh, Alexandra M. Z. Slawin, Andrew D. Smith

2020Chemical Science34 citationsDOIOpen Access PDF

Abstract

ring-opening and cyclisation, led to a range of 24 tetrahydroindolizine derivatives containing three stereocentres in up to >95 : 5 dr and >99 : 1 er.

Topics & Concepts

Enantioselective synthesisTandemCombinatorial chemistryCatalysisChemistryOrganic chemistryMaterials scienceComposite materialCyclopropane Reaction MechanismsSynthesis and Reactivity of HeterocyclesSynthesis and Characterization of Pyrroles